Local electronic and crystal structure of rare-earth cobalt phosphides RCo2P2 (R La, Ce, Pr, Nd, Eu) studied by XAFS and RIXS. Journal of Physics: Conference Series Volume 430, Issue 1, 2013, Article number 012132

14 сентября 2018
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Контактные данные автора публикации Yaroslavtsev, A.A.a , Menushenkov, A.P.a, Zaluzhnyy, I.A.a, Chernikov, R.V.b, Caliebe, W.b, Thompson, C.M.c, Arico, A.A.c, Kovnir, K.d, Shatruk, M.c a National Research Nuclear University MEPhI, Kashirskoe sh., 31, Moscow 115409, Russian Federa
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A detailed combined study of local electronic and crystal structures was performed for a series of rare-earth cobalt phosphides RCo2P 2 (R La, Ce, Pr, Nd, Eu) with peculiar itinerant magnetic ordering schemes using different methods employing the synchrotron radiation: RIXS, XANES and EXAFS. Europium and cerium are shown to be in the intermediate valence state in all compounds. The correlation between rare-earth valence and the observed changes of magnetic ordering in the systems under investigation is discussed.
Indexed keywords
Cobalt phosphide; EXAFS; Intermediate valence; Rare-earth valence; XAFS; XANES
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