Synthesis, crystal structure and physical properties of Ce 2Ru2Ga3. Intermetallics Volume 38, 2013, Pages 23-29
14 сентября 2018
202
| Предметная область | — |
| Выходные данные | — |
| Ключевые слова | — |
| Вид публикации | Статья |
| Контактные данные автора публикации | Murashova, E.a , Shablinskaya, K.a, Kurenbaeva, Z.a, Yaroslavtsev, A.b, Menushenkov, A.b, Chernikov, R.c, Grishina, O.b, Nesterenko, S.a, Seropegin, Y.a, Kaczorowski, D.d a Department of Chemistry, Moscow State Univ |
| Ссылка на публикацию в интернете | www.scopus.com/record/display.url?origin=recordpage&eid=2-s2.0-84875142195&citeCnt=3&noHighlight=false&sort=plf-f&src=s&st1=MEPhI&nlo=&nlr=&nls=&sid=F0743CC1BB1CEC168410A18CB87C48A7.Vdktg6RVtMfaQJ4pNTCQ:6500&sot=b&sdt=b&sl=31&s=AFFIL(MEPhI) AND PU |
Аннотация
The novel compound Ce2Ru2Ga3 was synthesized by arc-melting the elemental constituents in argon atmosphere followed by long-term annealing at 873 K. It forms in an orthorhombic system, with a crystal structure of new type (space group P212 121, Z = 4, oP28) and the lattice parameters: a = 4.488(2) Å, b = 6.912(4) Å, c = 17.092(9) Å. The gallide is structurally related to intermetallics crystallizing with the NdRh 2Sn4-type structure or its derivatives. It represents an unique family of materials with abnormally short Ce-Ru distances, which usually exhibit some instability of the valence state of cerium atoms. Based on the low-temperature magnetic and electrical transport data, as well as the X-ray absorption data, Ce2Ru2Ga3 has been characterised as another intermediate valence system. © 2013 Elsevier Ltd. All rights reserved.
--------------------------------------------------------------------------------
Author keywords
A. Rare-earth intermetallics; B. Crystal chemistry of intermetallics; B. Magnetic properties; F. Diffraction; F. Electron microprobe
--------------------------------------------------------------------------------
Indexed keywords
Crystal chemistry of intermetallics; Electrical transport; F. Diffraction; F. Electron microprobe; Intermediate valence; Orthorhombic systems; Rare earth intermetallics; Structure and physical properties
Подробнее--------------------------------------------------------------------------------
Author keywords
A. Rare-earth intermetallics; B. Crystal chemistry of intermetallics; B. Magnetic properties; F. Diffraction; F. Electron microprobe
--------------------------------------------------------------------------------
Indexed keywords
Crystal chemistry of intermetallics; Electrical transport; F. Diffraction; F. Electron microprobe; Intermediate valence; Orthorhombic systems; Rare earth intermetallics; Structure and physical properties
Для того чтобы оставить комментарий необходимо авторизоваться.